1,2-Dimetalated Benzene Derivatives (1,2-C6H4MCH3) n of Group 13 (M = Al, Ga, In)

1,2-Dimetalated Benzene Derivatives (1,2-C6H4MCH3) n of Group 13 (M = Al, Ga, In)

Reaction of (o-phenylene)magnesium (1) with CH3MCl2 (2; M = Al, Ga, In) gave access to the corresponding methyl(o-phenylene)metal compounds 3 ((1,2-C6H4MCH3) n ). These novel 1,2-dimetalated benzene derivatives of group 13 were characterized by their spectral data and, in the case of 3b (M = Ga, n =...

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Veröffentlicht in:Organometallics 1999-04, Vol.18 (9), p.1706-1709
Hauptverfasser: Dam, Matheus A, Nijbacker, Tom, de Kanter, Franciscus J. J, Akkerman, Otto S, Bickelhaupt, Friedrich, Spek, Anthony L
Format: Artikel
Sprache:eng
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Zusammenfassung:Reaction of (o-phenylene)magnesium (1) with CH3MCl2 (2; M = Al, Ga, In) gave access to the corresponding methyl(o-phenylene)metal compounds 3 ((1,2-C6H4MCH3) n ). These novel 1,2-dimetalated benzene derivatives of group 13 were characterized by their spectral data and, in the case of 3b (M = Ga, n = 2), by a single-crystal X-ray structure determination.
ISSN:0276-7333
1520-6041
DOI:10.1021/om9809217