Synthesis of Chiral Bis(phosphinite) Ligands with a Tetrahydrothiophene Backbone:  Use in Asymmetric Hydrogenation

A series of novel chiral nonracemic bis(phosphinites) derived from (R,R)-trans-2,5-tetrahydrothiophenedimethanol has been prepared. Reaction of these ligands, 6, with Rh(COD)2X (COD = cyclooctadiene, X = OS(O)2CF3, SbF6) yields rhodium complexes which have been tested in the asymmetric hydrogenation...

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Veröffentlicht in:	Organometallics 1998-11, Vol.17 (23), p.4976-4982
Hauptverfasser:	Hauptman, Elisabeth, Shapiro, Rafael, Marshall, William
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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