A Thermodynamically Based and Definitive Demonstration of the Inadequacy of the ECW Model for Phosphorus(III) Ligands

Isoequilibrium behavior arising from the temperature dependence of ΔG° of families of complexes containing phosphorus(III) ligands provides a diagnostic method for evaluating a model (used to describe ligand effects) and the associated set of stereoelectronic parameters. This evaluation is based not...

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Veröffentlicht in:Organometallics 1998-07, Vol.17 (15), p.3169-3175
Hauptverfasser: Fernandez, Anthony L, Lee, Tsung Ying, Reyes, Clementina, Prock, Alfred, Giering, Warren P
Format: Artikel
Sprache:eng
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