Reactions of Azines with Titanocene:  C−H Activation, C−C Coupling, and N−N Cleavage to Heterobimetallic Complexes

Reactions of Azines with Titanocene:  C−H Activation, C−C Coupling, and N−N Cleavage to Heterobimetallic Complexes

Either C−H activation or C−C coupling is observed in reactions of titanocene with azines (R1R2CN−NCR1R2), which lead to the formation of complexes 2 and 3, respectively. The reaction with two different metallocene units can yield heterobimetallic bis(alkylideneamido) complexes (4).

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Veröffentlicht in:Organometallics 1998-04, Vol.17 (9), p.1649-1651
Hauptverfasser: Ohff, Andreas, Zippel, Thorsten, Arndt, Perdita, Spannenberg, Anke, Kempe, Rhett, Rosenthal, Uwe
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container_end_page 1651
container_issue 9
container_start_page 1649
container_title Organometallics
container_volume 17
creator Ohff, Andreas
Zippel, Thorsten
Arndt, Perdita
Spannenberg, Anke
Kempe, Rhett
Rosenthal, Uwe
description Either C−H activation or C−C coupling is observed in reactions of titanocene with azines (R1R2CN−NCR1R2), which lead to the formation of complexes 2 and 3, respectively. The reaction with two different metallocene units can yield heterobimetallic bis(alkylideneamido) complexes (4).
doi_str_mv 10.1021/om9801251
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title Reactions of Azines with Titanocene:  C−H Activation, C−C Coupling, and N−N Cleavage to Heterobimetallic Complexes
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