Combined Use of Palladium-Catalyzed Carbon−Carbon and Metal−Carbon Bond Formations for the Construction of Poly(metallaacetylide) Tethers

Combined Use of Palladium-Catalyzed Carbon−Carbon and Metal−Carbon Bond Formations for the Construction of Poly(metallaacetylide) Tethers

The reaction between (η5-C5H4I)Fe(CO)2CH3 (2) and 2,5-bis[(trimethylstannyl)ethynyl]thiophene in the presence of palladium affords the iron which upon treatment with I2 is transformed to the corresponding (5). Reaction of the latter, in the presence of palladium, with the (trimethylstannyl)acetylide...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Organometallics 1998-06, Vol.17 (12), p.2574-2582
Hauptverfasser: Buttinelli, Andrea, Viola, Egidio, Antonelli, Eleonora, Lo Sterzo, Claudio
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 2582
container_issue 12
container_start_page 2574
container_title Organometallics
container_volume 17
creator Buttinelli, Andrea
Viola, Egidio
Antonelli, Eleonora
Lo Sterzo, Claudio
description The reaction between (η5-C5H4I)Fe(CO)2CH3 (2) and 2,5-bis[(trimethylstannyl)ethynyl]thiophene in the presence of palladium affords the iron which upon treatment with I2 is transformed to the corresponding (5). Reaction of the latter, in the presence of palladium, with the (trimethylstannyl)acetylide ML n = W(CO)3CH3, 9b, ML n = Re(CO)3) affords the polymetallaacetylide (10, ML n = W(CO)3CH3; 11, ML n = Re(CO)3). Trimethyltin derivatives of poly(ethynylthiophene) oligomers have been also prepared and tested for their use as spacers in poly(metallaacetylide) complexes.
doi_str_mv 10.1021/om971094x
format Article
fullrecord <record><control><sourceid>acs_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1021_om971094x</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>a607967213</sourcerecordid><originalsourceid>FETCH-LOGICAL-a361t-32267e48f6e1ac7ae2750ee567c5372f06224656ff9f1193dc8e5b450c4567883</originalsourceid><addsrcrecordid>eNptkL9OwzAQxi0EEqUw8AZekOgQ8J_ETkaIKCCVUqntwmK5ji1SkhjZqdTwBCwsPCJPgktRWZju7rvffdJ9AJxidIERwZe2zjhGWbzeAz2cEBQxFON90EOEs4hTSg_BkfdLhBDjlPTAR27rRdnoAs69htbAiawqWZSrOsplK6vuLaxy6Ra2-Xr_3DZQNgV80GH7J13boA2tq2Vb2sZDYx1snzXMw9C6ldqoP_a26s7rzW0lpdJtV5WFHsCZDrDzx-DAyMrrk9_aB_PhzSy_i0aPt_f51SiSlOE2ooQwruPUMI2l4lITniCtE8ZVQjkxiBESs4QZkxmMM1qoVCeLOEEqDkya0j4YbH2Vs947bcSrK2vpOoGR2OQodjkGNtqypW_1egdK9yJChDwRs8lUsOkT5ZNsLMaBP9vyUnmxtCvXhE_-8f0GNq-EZg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Combined Use of Palladium-Catalyzed Carbon−Carbon and Metal−Carbon Bond Formations for the Construction of Poly(metallaacetylide) Tethers</title><source>ACS Publications</source><creator>Buttinelli, Andrea ; Viola, Egidio ; Antonelli, Eleonora ; Lo Sterzo, Claudio</creator><creatorcontrib>Buttinelli, Andrea ; Viola, Egidio ; Antonelli, Eleonora ; Lo Sterzo, Claudio</creatorcontrib><description>The reaction between (η5-C5H4I)Fe(CO)2CH3 (2) and 2,5-bis[(trimethylstannyl)ethynyl]thiophene in the presence of palladium affords the iron which upon treatment with I2 is transformed to the corresponding (5). Reaction of the latter, in the presence of palladium, with the (trimethylstannyl)acetylide ML n = W(CO)3CH3, 9b, ML n = Re(CO)3) affords the polymetallaacetylide (10, ML n = W(CO)3CH3; 11, ML n = Re(CO)3). Trimethyltin derivatives of poly(ethynylthiophene) oligomers have been also prepared and tested for their use as spacers in poly(metallaacetylide) complexes.</description><identifier>ISSN: 0276-7333</identifier><identifier>EISSN: 1520-6041</identifier><identifier>DOI: 10.1021/om971094x</identifier><language>eng</language><publisher>American Chemical Society</publisher><ispartof>Organometallics, 1998-06, Vol.17 (12), p.2574-2582</ispartof><rights>Copyright © 1998 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a361t-32267e48f6e1ac7ae2750ee567c5372f06224656ff9f1193dc8e5b450c4567883</citedby><cites>FETCH-LOGICAL-a361t-32267e48f6e1ac7ae2750ee567c5372f06224656ff9f1193dc8e5b450c4567883</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/om971094x$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/om971094x$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,777,781,2752,27057,27905,27906,56719,56769</link.rule.ids></links><search><creatorcontrib>Buttinelli, Andrea</creatorcontrib><creatorcontrib>Viola, Egidio</creatorcontrib><creatorcontrib>Antonelli, Eleonora</creatorcontrib><creatorcontrib>Lo Sterzo, Claudio</creatorcontrib><title>Combined Use of Palladium-Catalyzed Carbon−Carbon and Metal−Carbon Bond Formations for the Construction of Poly(metallaacetylide) Tethers</title><title>Organometallics</title><addtitle>Organometallics</addtitle><description>The reaction between (η5-C5H4I)Fe(CO)2CH3 (2) and 2,5-bis[(trimethylstannyl)ethynyl]thiophene in the presence of palladium affords the iron which upon treatment with I2 is transformed to the corresponding (5). Reaction of the latter, in the presence of palladium, with the (trimethylstannyl)acetylide ML n = W(CO)3CH3, 9b, ML n = Re(CO)3) affords the polymetallaacetylide (10, ML n = W(CO)3CH3; 11, ML n = Re(CO)3). Trimethyltin derivatives of poly(ethynylthiophene) oligomers have been also prepared and tested for their use as spacers in poly(metallaacetylide) complexes.</description><issn>0276-7333</issn><issn>1520-6041</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1998</creationdate><recordtype>article</recordtype><recordid>eNptkL9OwzAQxi0EEqUw8AZekOgQ8J_ETkaIKCCVUqntwmK5ji1SkhjZqdTwBCwsPCJPgktRWZju7rvffdJ9AJxidIERwZe2zjhGWbzeAz2cEBQxFON90EOEs4hTSg_BkfdLhBDjlPTAR27rRdnoAs69htbAiawqWZSrOsplK6vuLaxy6Ra2-Xr_3DZQNgV80GH7J13boA2tq2Vb2sZDYx1snzXMw9C6ldqoP_a26s7rzW0lpdJtV5WFHsCZDrDzx-DAyMrrk9_aB_PhzSy_i0aPt_f51SiSlOE2ooQwruPUMI2l4lITniCtE8ZVQjkxiBESs4QZkxmMM1qoVCeLOEEqDkya0j4YbH2Vs947bcSrK2vpOoGR2OQodjkGNtqypW_1egdK9yJChDwRs8lUsOkT5ZNsLMaBP9vyUnmxtCvXhE_-8f0GNq-EZg</recordid><startdate>19980608</startdate><enddate>19980608</enddate><creator>Buttinelli, Andrea</creator><creator>Viola, Egidio</creator><creator>Antonelli, Eleonora</creator><creator>Lo Sterzo, Claudio</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19980608</creationdate><title>Combined Use of Palladium-Catalyzed Carbon−Carbon and Metal−Carbon Bond Formations for the Construction of Poly(metallaacetylide) Tethers</title><author>Buttinelli, Andrea ; Viola, Egidio ; Antonelli, Eleonora ; Lo Sterzo, Claudio</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a361t-32267e48f6e1ac7ae2750ee567c5372f06224656ff9f1193dc8e5b450c4567883</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1998</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Buttinelli, Andrea</creatorcontrib><creatorcontrib>Viola, Egidio</creatorcontrib><creatorcontrib>Antonelli, Eleonora</creatorcontrib><creatorcontrib>Lo Sterzo, Claudio</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><jtitle>Organometallics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Buttinelli, Andrea</au><au>Viola, Egidio</au><au>Antonelli, Eleonora</au><au>Lo Sterzo, Claudio</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Combined Use of Palladium-Catalyzed Carbon−Carbon and Metal−Carbon Bond Formations for the Construction of Poly(metallaacetylide) Tethers</atitle><jtitle>Organometallics</jtitle><addtitle>Organometallics</addtitle><date>1998-06-08</date><risdate>1998</risdate><volume>17</volume><issue>12</issue><spage>2574</spage><epage>2582</epage><pages>2574-2582</pages><issn>0276-7333</issn><eissn>1520-6041</eissn><abstract>The reaction between (η5-C5H4I)Fe(CO)2CH3 (2) and 2,5-bis[(trimethylstannyl)ethynyl]thiophene in the presence of palladium affords the iron which upon treatment with I2 is transformed to the corresponding (5). Reaction of the latter, in the presence of palladium, with the (trimethylstannyl)acetylide ML n = W(CO)3CH3, 9b, ML n = Re(CO)3) affords the polymetallaacetylide (10, ML n = W(CO)3CH3; 11, ML n = Re(CO)3). Trimethyltin derivatives of poly(ethynylthiophene) oligomers have been also prepared and tested for their use as spacers in poly(metallaacetylide) complexes.</abstract><pub>American Chemical Society</pub><doi>10.1021/om971094x</doi><tpages>9</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0276-7333
ispartof Organometallics, 1998-06, Vol.17 (12), p.2574-2582
issn 0276-7333
1520-6041
language eng
recordid cdi_crossref_primary_10_1021_om971094x
source ACS Publications
title Combined Use of Palladium-Catalyzed Carbon−Carbon and Metal−Carbon Bond Formations for the Construction of Poly(metallaacetylide) Tethers
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-20T11%3A19%3A10IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-acs_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Combined%20Use%20of%20Palladium-Catalyzed%20Carbon%E2%88%92Carbon%20and%20Metal%E2%88%92Carbon%20Bond%20Formations%20for%20the%20Construction%20of%20Poly(metallaacetylide)%20Tethers&rft.jtitle=Organometallics&rft.au=Buttinelli,%20Andrea&rft.date=1998-06-08&rft.volume=17&rft.issue=12&rft.spage=2574&rft.epage=2582&rft.pages=2574-2582&rft.issn=0276-7333&rft.eissn=1520-6041&rft_id=info:doi/10.1021/om971094x&rft_dat=%3Cacs_cross%3Ea607967213%3C/acs_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true