Synthesis and Solution and Solid-State Structures of Tris(pentafluorophenyl)borane Adducts of PhC(O)X (X = H, Me, OEt, NPr i 2)

Reaction of the highly electrophilic borane B(C6F5)3 with the carbonyl Lewis bases benzaldehyde, acetophenone, ethyl benzoate, and N,N-diisopropylbenzamide led to isolation of the crystalline adducts 1-H, 1-Me, 1-OEt, and 1-NPr, respectively, in good to excellent yields (63−89%). Equilibrium measure...

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Veröffentlicht in:	Organometallics 1998-03, Vol.17 (7), p.1369-1377
Hauptverfasser:	Parks, Daniel J, Piers, Warren E, Parvez, Masood, Atencio, Reinaldo, Zaworotko, Michael J
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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