Carbonylation of Amines with a Tungsten(IV) Carbonyl Complex
Reaction of [(CO)2W(NPh)I2]2 (1) with 2 equiv of piperidine yielded (CO)2W(NPh)I2(pip). In the presence of excess amine, secondary amines (R2NH) were carbonylated to the formamides R2NCHO while primary amines (R‘NH2) were converted to the ureas R‘NHCONHR‘.
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| Veröffentlicht in: | Organometallics 1997-08, Vol.16 (17), p.3863-3866 |
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| container_end_page | 3866 |
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| container_issue | 17 |
| container_start_page | 3863 |
| container_title | Organometallics |
| container_volume | 16 |
| creator | McCusker, Jennifer E Abboud, Khalil A McElwee-White, Lisa |
| description | Reaction of [(CO)2W(NPh)I2]2 (1) with 2 equiv of piperidine yielded (CO)2W(NPh)I2(pip). In the presence of excess amine, secondary amines (R2NH) were carbonylated to the formamides R2NCHO while primary amines (R‘NH2) were converted to the ureas R‘NHCONHR‘. |
| doi_str_mv | 10.1021/om970388f |
| format | Article |
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| identifier | ISSN: 0276-7333 |
| ispartof | Organometallics, 1997-08, Vol.16 (17), p.3863-3866 |
| issn | 0276-7333 1520-6041 |
| language | eng |
| recordid | cdi_crossref_primary_10_1021_om970388f |
| source | American Chemical Society Journals |
| title | Carbonylation of Amines with a Tungsten(IV) Carbonyl Complex |
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