Synthesis, Structure, and Reactivity of a Novel Hafnium Carboranyl Hydride Complex

The reaction of Cp*2(C2B9H11)2Hf2Me2 (1b; Cp* = C5Me5) with H2 yields the novel hafnium carboranyl hydride complex (Cp*)(η5-C2B9H11)Hf(μ-η5:η1-C2B9H10)Hf(Cp*)(H) (4), in which the two metal centers are linked by a C-metalated μ-η5:η1-C2B9H10 ligand and Hf−H−Hf and B−H−Hf bridges. Complex 4 catalyzes...

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Veröffentlicht in:	Organometallics 1997-04, Vol.16 (7), p.1349-1351
Hauptverfasser:	Yoshida, Masayasu, Crowther, Donna J, Jordan, Richard F
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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