Synthesis and Structure of Aryllithium Compounds Containing ortho-Directing (Dimethylamino)methyl and Trimethylhydrazino Substituents

The ortho-lithiated aryl compounds [2-Me2NCH2-4,6-(Me)2C6H2]2Li2·OEt2 (2) and [2-Me2N(Me)NC6H4]2Li2·TMEDA (6) have been prepared by metalation of the corresponding precursors 1 and 5. 6 is the first aryllithium derivative bearing a hydrazino group as coordinating ortho-substituent. Both organolithiu...

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Veröffentlicht in:	Organometallics 1997-01, Vol.16 (2), p.285-288
Hauptverfasser:	Belzner, Johannes, Schär, Dirk, Dehnert, Uwe, Noltemeyer, Mathias
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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