Isomer Distribution and Interconversion in Cationic Allylpalladium(II) Complexes with 2-(Iminomethyl)pyridine Ligands

The complexes [Pd(η3-allyl)(N-N‘)]ClO4 [allyl = 2-butenyl or 3-methyl-2-butenyl, N-N‘ = C5H3(6-R)N-2-CHNR‘ (R = H, R‘ = Me, CMe3, C6H4OMe-4; R = Me, R‘ = C6H4OMe-4) and C5H4N-2-CH2NMe2] are present in solution with different isomers, the structures of which may be assigned by an 1H NMR criterion ba...

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Veröffentlicht in:Organometallics 1997-02, Vol.16 (3), p.384-391
Hauptverfasser: Crociani, Bruno, Antonaroli, Simonetta, Paci, Maurizio, Di Bianca, Francesca, Canovese, Luciano
Format: Artikel
Sprache:eng
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