Hydrido(1,4,8,11,15,18,22,25-octa-n-pentylphthalocyaninato)- rhodium Dimers:  Single-Crystal X-ray Structure and the Isomerization of the Four Isomers

The hydrido(phthalocyaninato)rhodium dimer [(R8Pc)RhH]2 (1; R8Pc2- = dianion of 1,4,8,11,15,18,22,25-octa-n-pentylphthalocyanine) was synthesized from the reaction of [(R8Pc)(MeOH)2Rh]Cl with H2 at 110 °C in 1-pentanol. A single-crystal X-ray diffraction study shows that 1 is a dimer. The two Pc lig...

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Veröffentlicht in:	Organometallics 1996-04, Vol.15 (9), p.2338-2344
Hauptverfasser:	Chen, M. J, Nuñez, L, Rathke, J. W, Rogers, R. D
Format:	Artikel
Sprache:	eng
Schlagworte:	40 CHEMISTRY CRYSTAL STRUCTURE DIMERS ISOMERIZATION MOLECULAR STRUCTURE NMR SPECTRA ORGANOMETALLIC COMPOUNDS RHODIUM COMPLEXES STRUCTURAL CHEMICAL ANALYSIS SYNTHESIS X-RAY DIFFRACTION
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