Consequences of the Formation of an Organometallic Exciplex [Hg(η2-arene)] in Mercury-Photosensitized Reactions of Arenes:  C−C, C−O, and C−N Bond Cleavage

We have previously shown that mercury-photosensitized reactions give an unexpected C−C bond cleavage for PhCH2−CH3 and related aromatic systems. In this paper we report further theoretical and experimental studies that demonstrate the importance of organometallic intermediates of the type 3[Hg(η2-Ar...

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Veröffentlicht in:	Organometallics 1996-02, Vol.15 (4), p.1157-1165
Hauptverfasser:	Fowley, Lissa A, Lee, Jesse C, Crabtree, Robert H, Siegbahn, Per E. M
Format:	Artikel
Sprache:	eng
Schlagworte:	40 CHEMISTRY CHEMICAL BONDS CHEMICAL REACTION KINETICS CLEAVAGE DISSOCIATION ELECTRONIC STRUCTURE ENERGY LEVELS EXPERIMENTAL DATA HYDROCARBONS MERCURY COMPLEXES ORGANOMETALLIC COMPOUNDS PHOTOCHEMICAL REACTIONS PHYSICS
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