Reactions of [(CO)3Mn(η5-Thi)]+ (Thi = Thiophene or 2,5-Dimethylthiophene) with Nucleophiles

The η5-thiophene complexes, [(CO)3Mn(η5-T)]+ (1) and [(CO)3Mn(η5-2,5-Me2T)]+ (2), react with LiCuR2 (R = Me or Ph) by adding R- to the sulfur atom of the thiophene, which gives the η4-thiophene complexes, (CO)3Mn(η4-T·R) and (CO)3Mn(η4-2,5-Me2T·R). An X-ray study of (CO)3Mn(η4-T·C6H5) (6) shows the...

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Veröffentlicht in:	Organometallics 1996-01, Vol.15 (1), p.325-331
Hauptverfasser:	Chen, Jiabi, Young, Victor G, Angelici, Robert J
Format:	Artikel
Sprache:	eng
Schlagworte:	40 CHEMISTRY BOND ANGLE BOND LENGTHS CHEMICAL REACTIONS MANGANESE COMPLEXES MOLECULAR STRUCTURE NUMERICAL DATA ORGANOMETALLIC COMPOUNDS POLYCYCLIC SULFUR HETEROCYCLES THIOPHENE X-RAY DIFFRACTION
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