On the Nature of the Formation of [(η5-Ind)Ru(CO)2H]: Evidence of a Water-Gas Shift Reaction Mechanism via Triethylamine Reduction
The formation of [(η5-Ind)Ru(CO)2H] from [(η5-Ind)Ru(CO)3]+ was investigated using both 1H and 2H NMR spectroscopy and GC−mass spectrometry. Both NMR and GC-MS data support a water-gas shift reaction mechanism as the cause for formation of [(η5-Ind)Ru(CO)2H].
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| Veröffentlicht in: | Organometallics 2010-03, Vol.29 (5), p.1061-1063 |
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| container_end_page | 1063 |
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| container_issue | 5 |
| container_start_page | 1061 |
| container_title | Organometallics |
| container_volume | 29 |
| creator | Badger, Robert C D’Acchioli, Jason S Oudenhoven, Tracey A Walder, Brennan J |
| description | The formation of [(η5-Ind)Ru(CO)2H] from [(η5-Ind)Ru(CO)3]+ was investigated using both 1H and 2H NMR spectroscopy and GC−mass spectrometry. Both NMR and GC-MS data support a water-gas shift reaction mechanism as the cause for formation of [(η5-Ind)Ru(CO)2H]. |
| doi_str_mv | 10.1021/om9010774 |
| format | Article |
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| fulltext | fulltext |
| identifier | ISSN: 0276-7333 |
| ispartof | Organometallics, 2010-03, Vol.29 (5), p.1061-1063 |
| issn | 0276-7333 1520-6041 |
| language | eng |
| recordid | cdi_crossref_primary_10_1021_om9010774 |
| source | ACS Publications |
| title | On the Nature of the Formation of [(η5-Ind)Ru(CO)2H]: Evidence of a Water-Gas Shift Reaction Mechanism via Triethylamine Reduction |
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