Isocyanide-Promoted Ylidene Transfer to Phosphorus: Rearrangement in the First-Generation Grubbs Complex
Carbon monoxide or an aryl isocyanide promotes a benzylidene carbene transfer from ruthenium to tricyclohexylphosphine in the first-generation Grubbs carbene complex. The resulting ruthenium(II) complexes have been isolated and structurally characterized by X-ray crystal structure analysis; a probab...
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Veröffentlicht in: | Organometallics 2008-08, Vol.27 (15), p.3630-3632 |
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creator | Galan, Brandon R Pitak, Mateusz Keister, Jerome B Diver, Steven T |
description | Carbon monoxide or an aryl isocyanide promotes a benzylidene carbene transfer from ruthenium to tricyclohexylphosphine in the first-generation Grubbs carbene complex. The resulting ruthenium(II) complexes have been isolated and structurally characterized by X-ray crystal structure analysis; a probable mechanism for the ligand-promoted transformation is also discussed. |
doi_str_mv | 10.1021/om8003652 |
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title | Isocyanide-Promoted Ylidene Transfer to Phosphorus: Rearrangement in the First-Generation Grubbs Complex |
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