Synthesis of the Ruthenaboratranes [Ru(CS)(PPh3){B(mt)3}](Ru→B)8 and [Ru(CO)(CNR){B(mt)3}](Ru→B)8 (mt = methimazolyl, R = t Bu, C6H3Me2-2,6, C6H2Me3-2,4,6)
The reaction of [Ru(CHCH2)Cl(CS)(PPh3)2] with Na[HB(mt)3] (mt = methimazolyl) provides the ruthenaboratrane [Ru(CS)(PPh3){B(mt)3}]. The reaction of [Ru(CO)(PPh3){B(mt)3}] with CO to provide [Ru(CO)2{B(mt)3}] is reversible, while the phosphine-free ruthenaboratranes [Ru(CO)(CNR){B(mt)3}] (R = t Bu,...
Gespeichert in:
| Veröffentlicht in: | Organometallics 2008-02, Vol.27 (3), p.381-386 |
|---|---|
| Hauptverfasser: | , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 386 |
|---|---|
| container_issue | 3 |
| container_start_page | 381 |
| container_title | Organometallics |
| container_volume | 27 |
| creator | Crossley, Ian R Foreman, Mark R. St.-J Hill, Anthony F Owen, Gareth R White, Andrew J. P Williams, David J Willis, Anthony C |
| description | The reaction of [Ru(CHCH2)Cl(CS)(PPh3)2] with Na[HB(mt)3] (mt = methimazolyl) provides the ruthenaboratrane [Ru(CS)(PPh3){B(mt)3}]. The reaction of [Ru(CO)(PPh3){B(mt)3}] with CO to provide [Ru(CO)2{B(mt)3}] is reversible, while the phosphine-free ruthenaboratranes [Ru(CO)(CNR){B(mt)3}] (R = t Bu, C6H3Me2-2,6, C6H2Me3-2,4,6) form irreversibly upon addition of isonitriles (CNR) to [Ru(CO)(PPh3){B(mt)3}]. The crystal structures of the ruthenaboratranes [Ru(CS)(PPh3){B(mt)3}], [Ru(CO)(CN t Bu)({B(mt)3}], and [Ru(CO)(CNC6H2Me3-2,4,6){B(mt)3}] are reported. |
| doi_str_mv | 10.1021/om7008777 |
| format | Article |
| fullrecord | <record><control><sourceid>acs_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1021_om7008777</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>b403990606</sourcerecordid><originalsourceid>FETCH-LOGICAL-a2084-11106bead5e197d3bc41ff8d72226648d055bf5734606f910e372e159463ad3</originalsourceid><addsrcrecordid>eNptkM1Kw0AUhQdRsFYXvsFshAQSnZ9kJl24MEGt0D-TrhQZJs2EtraJZBKwilsfwBfw3XwSRyOuurn3nsPH5d4DwDFGpxgRfFauOUIB53wHdLBPkMuQh3dBBxHOXE4p3QcHWi8RQoxT0gGfyaao50ovNCxzaCYYN6YWMi0rWVeyUBrex40VJbY1mcyp_Rpa69qmbw9W3Hy9f4R2AGWRtczYtqJRvA0xBjyHa1XPF2v5Uq42KwfGxqlh2DgwYn06VMQlDvsVZKioEZ7D7EOwl8uVVkd_vQuSq8tp1HcH4-ub6GLgSoICz8UYI5YqmfkK93hG05mH8zzIOCGEMS_IkO-nuc-pxxDLexgpyonCfs9jVGa0C-x266wqta5ULp4qc2i1ERiJn1zFf66GdVt2oWv1_A_K6lGYSLkvppNEDL0I343Cqbg1_EnLy5kWy7KpCvPHlr3fHZB_Vg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Synthesis of the Ruthenaboratranes [Ru(CS)(PPh3){B(mt)3}](Ru→B)8 and [Ru(CO)(CNR){B(mt)3}](Ru→B)8 (mt = methimazolyl, R = t Bu, C6H3Me2-2,6, C6H2Me3-2,4,6)</title><source>ACS Publications</source><creator>Crossley, Ian R ; Foreman, Mark R. St.-J ; Hill, Anthony F ; Owen, Gareth R ; White, Andrew J. P ; Williams, David J ; Willis, Anthony C</creator><creatorcontrib>Crossley, Ian R ; Foreman, Mark R. St.-J ; Hill, Anthony F ; Owen, Gareth R ; White, Andrew J. P ; Williams, David J ; Willis, Anthony C</creatorcontrib><description>The reaction of [Ru(CHCH2)Cl(CS)(PPh3)2] with Na[HB(mt)3] (mt = methimazolyl) provides the ruthenaboratrane [Ru(CS)(PPh3){B(mt)3}]. The reaction of [Ru(CO)(PPh3){B(mt)3}] with CO to provide [Ru(CO)2{B(mt)3}] is reversible, while the phosphine-free ruthenaboratranes [Ru(CO)(CNR){B(mt)3}] (R = t Bu, C6H3Me2-2,6, C6H2Me3-2,4,6) form irreversibly upon addition of isonitriles (CNR) to [Ru(CO)(PPh3){B(mt)3}]. The crystal structures of the ruthenaboratranes [Ru(CS)(PPh3){B(mt)3}], [Ru(CO)(CN t Bu)({B(mt)3}], and [Ru(CO)(CNC6H2Me3-2,4,6){B(mt)3}] are reported.</description><identifier>ISSN: 0276-7333</identifier><identifier>EISSN: 1520-6041</identifier><identifier>DOI: 10.1021/om7008777</identifier><language>eng</language><publisher>American Chemical Society</publisher><ispartof>Organometallics, 2008-02, Vol.27 (3), p.381-386</ispartof><rights>Copyright © 2008 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a2084-11106bead5e197d3bc41ff8d72226648d055bf5734606f910e372e159463ad3</citedby><cites>FETCH-LOGICAL-a2084-11106bead5e197d3bc41ff8d72226648d055bf5734606f910e372e159463ad3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/om7008777$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/om7008777$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,776,780,2751,27055,27903,27904,56717,56767</link.rule.ids></links><search><creatorcontrib>Crossley, Ian R</creatorcontrib><creatorcontrib>Foreman, Mark R. St.-J</creatorcontrib><creatorcontrib>Hill, Anthony F</creatorcontrib><creatorcontrib>Owen, Gareth R</creatorcontrib><creatorcontrib>White, Andrew J. P</creatorcontrib><creatorcontrib>Williams, David J</creatorcontrib><creatorcontrib>Willis, Anthony C</creatorcontrib><title>Synthesis of the Ruthenaboratranes [Ru(CS)(PPh3){B(mt)3}](Ru→B)8 and [Ru(CO)(CNR){B(mt)3}](Ru→B)8 (mt = methimazolyl, R = t Bu, C6H3Me2-2,6, C6H2Me3-2,4,6)</title><title>Organometallics</title><addtitle>Organometallics</addtitle><description>The reaction of [Ru(CHCH2)Cl(CS)(PPh3)2] with Na[HB(mt)3] (mt = methimazolyl) provides the ruthenaboratrane [Ru(CS)(PPh3){B(mt)3}]. The reaction of [Ru(CO)(PPh3){B(mt)3}] with CO to provide [Ru(CO)2{B(mt)3}] is reversible, while the phosphine-free ruthenaboratranes [Ru(CO)(CNR){B(mt)3}] (R = t Bu, C6H3Me2-2,6, C6H2Me3-2,4,6) form irreversibly upon addition of isonitriles (CNR) to [Ru(CO)(PPh3){B(mt)3}]. The crystal structures of the ruthenaboratranes [Ru(CS)(PPh3){B(mt)3}], [Ru(CO)(CN t Bu)({B(mt)3}], and [Ru(CO)(CNC6H2Me3-2,4,6){B(mt)3}] are reported.</description><issn>0276-7333</issn><issn>1520-6041</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNptkM1Kw0AUhQdRsFYXvsFshAQSnZ9kJl24MEGt0D-TrhQZJs2EtraJZBKwilsfwBfw3XwSRyOuurn3nsPH5d4DwDFGpxgRfFauOUIB53wHdLBPkMuQh3dBBxHOXE4p3QcHWi8RQoxT0gGfyaao50ovNCxzaCYYN6YWMi0rWVeyUBrex40VJbY1mcyp_Rpa69qmbw9W3Hy9f4R2AGWRtczYtqJRvA0xBjyHa1XPF2v5Uq42KwfGxqlh2DgwYn06VMQlDvsVZKioEZ7D7EOwl8uVVkd_vQuSq8tp1HcH4-ub6GLgSoICz8UYI5YqmfkK93hG05mH8zzIOCGEMS_IkO-nuc-pxxDLexgpyonCfs9jVGa0C-x266wqta5ULp4qc2i1ERiJn1zFf66GdVt2oWv1_A_K6lGYSLkvppNEDL0I343Cqbg1_EnLy5kWy7KpCvPHlr3fHZB_Vg</recordid><startdate>20080211</startdate><enddate>20080211</enddate><creator>Crossley, Ian R</creator><creator>Foreman, Mark R. St.-J</creator><creator>Hill, Anthony F</creator><creator>Owen, Gareth R</creator><creator>White, Andrew J. P</creator><creator>Williams, David J</creator><creator>Willis, Anthony C</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20080211</creationdate><title>Synthesis of the Ruthenaboratranes [Ru(CS)(PPh3){B(mt)3}](Ru→B)8 and [Ru(CO)(CNR){B(mt)3}](Ru→B)8 (mt = methimazolyl, R = t Bu, C6H3Me2-2,6, C6H2Me3-2,4,6)</title><author>Crossley, Ian R ; Foreman, Mark R. St.-J ; Hill, Anthony F ; Owen, Gareth R ; White, Andrew J. P ; Williams, David J ; Willis, Anthony C</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a2084-11106bead5e197d3bc41ff8d72226648d055bf5734606f910e372e159463ad3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Crossley, Ian R</creatorcontrib><creatorcontrib>Foreman, Mark R. St.-J</creatorcontrib><creatorcontrib>Hill, Anthony F</creatorcontrib><creatorcontrib>Owen, Gareth R</creatorcontrib><creatorcontrib>White, Andrew J. P</creatorcontrib><creatorcontrib>Williams, David J</creatorcontrib><creatorcontrib>Willis, Anthony C</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><jtitle>Organometallics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Crossley, Ian R</au><au>Foreman, Mark R. St.-J</au><au>Hill, Anthony F</au><au>Owen, Gareth R</au><au>White, Andrew J. P</au><au>Williams, David J</au><au>Willis, Anthony C</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of the Ruthenaboratranes [Ru(CS)(PPh3){B(mt)3}](Ru→B)8 and [Ru(CO)(CNR){B(mt)3}](Ru→B)8 (mt = methimazolyl, R = t Bu, C6H3Me2-2,6, C6H2Me3-2,4,6)</atitle><jtitle>Organometallics</jtitle><addtitle>Organometallics</addtitle><date>2008-02-11</date><risdate>2008</risdate><volume>27</volume><issue>3</issue><spage>381</spage><epage>386</epage><pages>381-386</pages><issn>0276-7333</issn><eissn>1520-6041</eissn><abstract>The reaction of [Ru(CHCH2)Cl(CS)(PPh3)2] with Na[HB(mt)3] (mt = methimazolyl) provides the ruthenaboratrane [Ru(CS)(PPh3){B(mt)3}]. The reaction of [Ru(CO)(PPh3){B(mt)3}] with CO to provide [Ru(CO)2{B(mt)3}] is reversible, while the phosphine-free ruthenaboratranes [Ru(CO)(CNR){B(mt)3}] (R = t Bu, C6H3Me2-2,6, C6H2Me3-2,4,6) form irreversibly upon addition of isonitriles (CNR) to [Ru(CO)(PPh3){B(mt)3}]. The crystal structures of the ruthenaboratranes [Ru(CS)(PPh3){B(mt)3}], [Ru(CO)(CN t Bu)({B(mt)3}], and [Ru(CO)(CNC6H2Me3-2,4,6){B(mt)3}] are reported.</abstract><pub>American Chemical Society</pub><doi>10.1021/om7008777</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0276-7333 |
| ispartof | Organometallics, 2008-02, Vol.27 (3), p.381-386 |
| issn | 0276-7333 1520-6041 |
| language | eng |
| recordid | cdi_crossref_primary_10_1021_om7008777 |
| source | ACS Publications |
| title | Synthesis of the Ruthenaboratranes [Ru(CS)(PPh3){B(mt)3}](Ru→B)8 and [Ru(CO)(CNR){B(mt)3}](Ru→B)8 (mt = methimazolyl, R = t Bu, C6H3Me2-2,6, C6H2Me3-2,4,6) |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-21T18%3A17%3A07IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-acs_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis%20of%20the%20Ruthenaboratranes%20%5BRu(CS)(PPh3)%7BB(mt)3%7D%5D(Ru%E2%86%92B)8%20and%20%5BRu(CO)(CNR)%7BB(mt)3%7D%5D(Ru%E2%86%92B)8%20(mt%20=%20methimazolyl,%20R%20=%20t%20Bu,%20C6H3Me2-2,6,%20C6H2Me3-2,4,6)&rft.jtitle=Organometallics&rft.au=Crossley,%20Ian%20R&rft.date=2008-02-11&rft.volume=27&rft.issue=3&rft.spage=381&rft.epage=386&rft.pages=381-386&rft.issn=0276-7333&rft.eissn=1520-6041&rft_id=info:doi/10.1021/om7008777&rft_dat=%3Cacs_cross%3Eb403990606%3C/acs_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |