Arene Binding Affinities in [CpRu(η6-arene)]+ Complexes: Models for the Adsorption of Arenes on Hydrodesulfurization Catalysts

Product/reactant ratios (Y) were determined for the reactions CpRu(η6-DBT)+ + L ⇌ CpRu(η6-L)+ + DBT (where DBT is dibenzothiophene and L is a homo- or heterocyclic arene), which were conducted under UV photolysis conditions. In the photostationary state, the Y values for the different arenes decreas...

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Veröffentlicht in:Organometallics 2008-03, Vol.27 (6), p.1098-1105
Hauptverfasser: Choi, Moon-Gun, Ho, Teh C, Angelici, Robert J
Format: Artikel
Sprache:eng
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