Hydrolysis and Methanolysis of Silanes Catalyzed by Iridium(III) Bis-N-Heterocyclic Carbene Complexes: Influence of the Wingtip Groups

New [Ir­(CH3CN)2(I)2{κC,C′-bis­(NHC)}]­BF4 complexes featuring bis-NHC ligands with a methylene bridge and different N substitution (−CH2CH2CH2CH3 and −CH2CH2OPh) were synthesized. NMR studies and X-ray diffraction structures evidenced that the wingtip group −CH2CH2OPh presents a hemilabile behavior...

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Veröffentlicht in:	Organometallics 2015-06, Vol.34 (11), p.2378-2385
Hauptverfasser:	Aliaga-Lavrijsen, Mélanie, Iglesias, Manuel, Cebollada, Andrea, Garcés, Karin, Garcı́a, Nestor, Sanz Miguel, Pablo J, Fernández-Alvarez, Francisco J, Pérez-Torrente, Jesús J, Oro, Luis A
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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