Iridium Half-Sandwich Complexes with Di- and Tridentate Bis(pyridylimino)isoindolato Ligands: Stoichiometric and Catalytic Reactivity

A series of κ2-(N,N)-coordinated bis­(2-pyridylimino)­isoindolato (BPI) complexes [Cp*Ir­(BPI)­Cl], which possess “three-legged piano-stool” structures, with the iridium atom being coordinated by the Cp* ligand 2 × N and Cl, were prepared via deprotonation of the BPIH ligands with either potassium h...

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Veröffentlicht in:Organometallics 2015-06, Vol.34 (11), p.2326-2342
Hauptverfasser: Müller, Astrid L, Bleith, Tim, Roth, Torsten, Wadepohl, Hubert, Gade, Lutz H
Format: Artikel
Sprache:eng
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