Hexanuclear Cylinder-Shaped Assemblies of Silver and Gold from Benzene–Hexa-N-heterocyclic Carbenes

Hexanuclear Cylinder-Shaped Assemblies of Silver and Gold from Benzene–Hexa-N-heterocyclic Carbenes

In this work we describe the preparation of a new benzene–hexaimidazolylidene ligand, which we have coordinated to silver and gold. The new complexes constitute unique examples of cylinder-like macromolecular arrangements, in which six metal atoms are sandwiched between two hexacarbene ligands.

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Veröffentlicht in:Organometallics 2014-10, Vol.33 (19), p.5077-5080
Hauptverfasser: Segarra, Candela, Guisado-Barrios, Gregorio, Hahn, F. Ekkehardt, Peris, Eduardo
Format: Artikel
Sprache:eng
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Zusammenfassung:In this work we describe the preparation of a new benzene–hexaimidazolylidene ligand, which we have coordinated to silver and gold. The new complexes constitute unique examples of cylinder-like macromolecular arrangements, in which six metal atoms are sandwiched between two hexacarbene ligands.
ISSN:0276-7333
1520-6041
DOI:10.1021/om500729b