Revisiting the Synthesis and Elucidating the Structure of Potassium Cyclopentadienyldicarbonylruthenate, K[CpRu(CO)2]

Known procedures for the synthesis of K[CpRu(CO)2] (KRp) via reductive cleavage of the ruthenium dimer Rp2 were found to be inconsistent and have thus been revisited, and a revised protocol using K[HB(sec-Bu)3] (K-Selectride) as the reducing agent is now reported that gives yellow KRp in crystalline...

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Veröffentlicht in:Organometallics 2014-03, Vol.33 (6), p.1475-1479
Hauptverfasser: Kalz, Kai F, Kindermann, Nicole, Xiang, Sheng-Qi, Kronz, Andreas, Lange, Adam, Meyer, Franc
Format: Artikel
Sprache:eng
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