Revisiting the Synthesis and Elucidating the Structure of Potassium Cyclopentadienyldicarbonylruthenate, K[CpRu(CO)2]
Known procedures for the synthesis of K[CpRu(CO)2] (KRp) via reductive cleavage of the ruthenium dimer Rp2 were found to be inconsistent and have thus been revisited, and a revised protocol using K[HB(sec-Bu)3] (K-Selectride) as the reducing agent is now reported that gives yellow KRp in crystalline...
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Veröffentlicht in: | Organometallics 2014-03, Vol.33 (6), p.1475-1479 |
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Hauptverfasser: | , , , , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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