New Diruthenium Bis-alkynyl Compounds as Potential Ditopic Linkers

The reaction between Ru2(ap)4-CC-4-C6H4-P(O)(O t Bu)2 and LiC2X afforded trans-XC2-Ru2(ap)4-CC-4-C6H4–P(O)(O t Bu)2, where X is −SiMe3 (1), −C2SiMe3 (2), −C4H (3), or −4-C6H4C2SiMe3 (4). Compound 5, trans-( t BuO)2(O)P-C6H4-4-CC-Ru2(ap)4-CC-4-C6H4SC2H4SiMe3, was obtained from the reaction betwee...

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Veröffentlicht in:	Organometallics 2013-11, Vol.32 (21), p.6461-6467
Hauptverfasser:	Savchenko, Julia, Cao, Zhi, Natoli, Sean N, Cummings, Steven P, Prentice, Boone M, Fanwick, Phillip E, Ren, Tong
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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