Efficient Synthesis of an Unprecedented Enantiopure Hybrid Scorpionate/Cyclopentadienyl by Diastereoselective Nucleophilic Addition to a Fulvene

The work described here represents the first example of an enantiopure hybrid scorpionate/cyclopentadiene ligand. The ligand was obtained in a one-pot synthetic procedure by an efficient and highly diastereoselective nucleophilic addition of an organolithium reagent to an electrophilically activated...

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Veröffentlicht in:Organometallics 2013-06, Vol.32 (12), p.3437-3440
Hauptverfasser: Honrado, Manuel, Otero, Antonio, Fernández-Baeza, Juan, Sánchez-Barba, Luis F, Lara-Sánchez, Agustı́n, Tejeda, Juan, Carrión, Marı́a P, Martı́nez-Ferrer, Jaime, Garcés, Andrés, Rodrı́guez, Ana M
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Sprache:eng
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