Simple Polyphenyl Zirconium and Hafnium Metallocene Room-Temperature Lumophores for Cell Imaging
Zirconium and hafnium metallocene dihalides based on simple polyphenyl cyclopentadienes are stable room-temperature lumophores with large Stokes shifts, emitting from states with substantial LMCT character. Their synthesis is described, including by a rapid solvent-free approach compatible with the...
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| Veröffentlicht in: | Organometallics 2013-06, Vol.32 (12), p.3566-3569 |
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| container_end_page | 3569 |
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| container_issue | 12 |
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| container_title | Organometallics |
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| creator | Pritchard, Victoria E Thorp-Greenwood, Flora L Balasingham, Rebeca G Williams, Catrin F Kariuki, Benson M Platts, James A Hallett, Andrew J Coogan, Michael P |
| description | Zirconium and hafnium metallocene dihalides based on simple polyphenyl cyclopentadienes are stable room-temperature lumophores with large Stokes shifts, emitting from states with substantial LMCT character. Their synthesis is described, including by a rapid solvent-free approach compatible with the lifetime of PET-active isotopes (89Zr). Preliminary experiments indicate the viability of these species as lumophores for fluorescence cell-imaging microscopy. |
| doi_str_mv | 10.1021/om400212y |
| format | Article |
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| fulltext | fulltext |
| identifier | ISSN: 0276-7333 |
| ispartof | Organometallics, 2013-06, Vol.32 (12), p.3566-3569 |
| issn | 0276-7333 1520-6041 |
| language | eng |
| recordid | cdi_crossref_primary_10_1021_om400212y |
| source | American Chemical Society (ACS) Journals |
| title | Simple Polyphenyl Zirconium and Hafnium Metallocene Room-Temperature Lumophores for Cell Imaging |
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