Base-Free, Acceptorless, and Chemoselective Alcohol Dehydrogenation Catalyzed by an Amide-Derived NNN-Ruthenium(II) Hydride Complex
The bmpi (1,3-bis(6′-methyl-2′-pyridylimino)isoindoline) pincer Ru(II) hydride complex catalyzes base-free, acceptorless, and chemoselective dehydrogenation of alcohols with liberation of dihydrogen under moderate (
Gespeichert in:
| Veröffentlicht in: | Organometallics 2013-04, Vol.32 (7), p.2046-2049 |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 2049 |
|---|---|
| container_issue | 7 |
| container_start_page | 2046 |
| container_title | Organometallics |
| container_volume | 32 |
| creator | Tseng, Kuei-Nin T Kampf, Jeff W Szymczak, Nathaniel K |
| description | The bmpi (1,3-bis(6′-methyl-2′-pyridylimino)isoindoline) pincer Ru(II) hydride complex catalyzes base-free, acceptorless, and chemoselective dehydrogenation of alcohols with liberation of dihydrogen under moderate ( |
| doi_str_mv | 10.1021/om4000677 |
| format | Article |
| fullrecord | <record><control><sourceid>acs_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1021_om4000677</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>a31895259</sourcerecordid><originalsourceid>FETCH-LOGICAL-a325t-a34ab715c21f1f43ca95e1652fdd048766851f00f0ef40d57ff6bf9b5c84ac043</originalsourceid><addsrcrecordid>eNptkEFLwzAYhoMoOKcH_0EugoNVv7RJux1n59xgTBA9lzT5YjvaZiSdWK_-casTT17e7_I8Hy8vIZcMbhiE7NbWHADiJDkiAyZCCGLg7JgMIEziIImi6JSceb_9YaJwQD7vpMdg4RDHdKYU7lrrKvR-TGWjaVpgbT1WqNryDemsUrawFZ1j0WlnX7GRbWkbmspWVt0Happ3vUdndakxmKPrJU03m03wtG8LbMp9fb1ajeiyt3uCprbeVfh-Tk6MrDxe_N4heVncP6fLYP34sEpn60BGoWj75DJPmFAhM8zwSMmpQBaL0GgNfJLE8UQwA2AADQctEmPi3ExzoSZcKuDRkIwOf5Wz3js02c6VtXRdxiD7Xi_7W69nrw6sVD7b2r1r-mb_cF9uF26d</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Base-Free, Acceptorless, and Chemoselective Alcohol Dehydrogenation Catalyzed by an Amide-Derived NNN-Ruthenium(II) Hydride Complex</title><source>American Chemical Society Journals</source><creator>Tseng, Kuei-Nin T ; Kampf, Jeff W ; Szymczak, Nathaniel K</creator><creatorcontrib>Tseng, Kuei-Nin T ; Kampf, Jeff W ; Szymczak, Nathaniel K</creatorcontrib><description>The bmpi (1,3-bis(6′-methyl-2′-pyridylimino)isoindoline) pincer Ru(II) hydride complex catalyzes base-free, acceptorless, and chemoselective dehydrogenation of alcohols with liberation of dihydrogen under moderate (<120 °C) conditions. Primary alcohols and diols are converted to ester and lactone products with high conversion efficiencies. The catalyst system is remarkably selective for the oxidation of secondary alcohols in the presence of primary alcohols.</description><identifier>ISSN: 0276-7333</identifier><identifier>EISSN: 1520-6041</identifier><identifier>DOI: 10.1021/om4000677</identifier><language>eng</language><publisher>American Chemical Society</publisher><ispartof>Organometallics, 2013-04, Vol.32 (7), p.2046-2049</ispartof><rights>Copyright © 2013 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a325t-a34ab715c21f1f43ca95e1652fdd048766851f00f0ef40d57ff6bf9b5c84ac043</citedby><cites>FETCH-LOGICAL-a325t-a34ab715c21f1f43ca95e1652fdd048766851f00f0ef40d57ff6bf9b5c84ac043</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/om4000677$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/om4000677$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>315,782,786,2767,27083,27931,27932,56745,56795</link.rule.ids></links><search><creatorcontrib>Tseng, Kuei-Nin T</creatorcontrib><creatorcontrib>Kampf, Jeff W</creatorcontrib><creatorcontrib>Szymczak, Nathaniel K</creatorcontrib><title>Base-Free, Acceptorless, and Chemoselective Alcohol Dehydrogenation Catalyzed by an Amide-Derived NNN-Ruthenium(II) Hydride Complex</title><title>Organometallics</title><addtitle>Organometallics</addtitle><description>The bmpi (1,3-bis(6′-methyl-2′-pyridylimino)isoindoline) pincer Ru(II) hydride complex catalyzes base-free, acceptorless, and chemoselective dehydrogenation of alcohols with liberation of dihydrogen under moderate (<120 °C) conditions. Primary alcohols and diols are converted to ester and lactone products with high conversion efficiencies. The catalyst system is remarkably selective for the oxidation of secondary alcohols in the presence of primary alcohols.</description><issn>0276-7333</issn><issn>1520-6041</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNptkEFLwzAYhoMoOKcH_0EugoNVv7RJux1n59xgTBA9lzT5YjvaZiSdWK_-casTT17e7_I8Hy8vIZcMbhiE7NbWHADiJDkiAyZCCGLg7JgMIEziIImi6JSceb_9YaJwQD7vpMdg4RDHdKYU7lrrKvR-TGWjaVpgbT1WqNryDemsUrawFZ1j0WlnX7GRbWkbmspWVt0Happ3vUdndakxmKPrJU03m03wtG8LbMp9fb1ajeiyt3uCprbeVfh-Tk6MrDxe_N4heVncP6fLYP34sEpn60BGoWj75DJPmFAhM8zwSMmpQBaL0GgNfJLE8UQwA2AADQctEmPi3ExzoSZcKuDRkIwOf5Wz3js02c6VtXRdxiD7Xi_7W69nrw6sVD7b2r1r-mb_cF9uF26d</recordid><startdate>20130408</startdate><enddate>20130408</enddate><creator>Tseng, Kuei-Nin T</creator><creator>Kampf, Jeff W</creator><creator>Szymczak, Nathaniel K</creator><general>American Chemical Society</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20130408</creationdate><title>Base-Free, Acceptorless, and Chemoselective Alcohol Dehydrogenation Catalyzed by an Amide-Derived NNN-Ruthenium(II) Hydride Complex</title><author>Tseng, Kuei-Nin T ; Kampf, Jeff W ; Szymczak, Nathaniel K</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a325t-a34ab715c21f1f43ca95e1652fdd048766851f00f0ef40d57ff6bf9b5c84ac043</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Tseng, Kuei-Nin T</creatorcontrib><creatorcontrib>Kampf, Jeff W</creatorcontrib><creatorcontrib>Szymczak, Nathaniel K</creatorcontrib><collection>CrossRef</collection><jtitle>Organometallics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Tseng, Kuei-Nin T</au><au>Kampf, Jeff W</au><au>Szymczak, Nathaniel K</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Base-Free, Acceptorless, and Chemoselective Alcohol Dehydrogenation Catalyzed by an Amide-Derived NNN-Ruthenium(II) Hydride Complex</atitle><jtitle>Organometallics</jtitle><addtitle>Organometallics</addtitle><date>2013-04-08</date><risdate>2013</risdate><volume>32</volume><issue>7</issue><spage>2046</spage><epage>2049</epage><pages>2046-2049</pages><issn>0276-7333</issn><eissn>1520-6041</eissn><abstract>The bmpi (1,3-bis(6′-methyl-2′-pyridylimino)isoindoline) pincer Ru(II) hydride complex catalyzes base-free, acceptorless, and chemoselective dehydrogenation of alcohols with liberation of dihydrogen under moderate (<120 °C) conditions. Primary alcohols and diols are converted to ester and lactone products with high conversion efficiencies. The catalyst system is remarkably selective for the oxidation of secondary alcohols in the presence of primary alcohols.</abstract><pub>American Chemical Society</pub><doi>10.1021/om4000677</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0276-7333 |
| ispartof | Organometallics, 2013-04, Vol.32 (7), p.2046-2049 |
| issn | 0276-7333 1520-6041 |
| language | eng |
| recordid | cdi_crossref_primary_10_1021_om4000677 |
| source | American Chemical Society Journals |
| title | Base-Free, Acceptorless, and Chemoselective Alcohol Dehydrogenation Catalyzed by an Amide-Derived NNN-Ruthenium(II) Hydride Complex |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-04T22%3A22%3A39IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-acs_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Base-Free,%20Acceptorless,%20and%20Chemoselective%20Alcohol%20Dehydrogenation%20Catalyzed%20by%20an%20Amide-Derived%20NNN-Ruthenium(II)%20Hydride%20Complex&rft.jtitle=Organometallics&rft.au=Tseng,%20Kuei-Nin%20T&rft.date=2013-04-08&rft.volume=32&rft.issue=7&rft.spage=2046&rft.epage=2049&rft.pages=2046-2049&rft.issn=0276-7333&rft.eissn=1520-6041&rft_id=info:doi/10.1021/om4000677&rft_dat=%3Cacs_cross%3Ea31895259%3C/acs_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |