Ruthenium(II) Arene Complexes with Asymmetrical Guanidinate Ligands: Synthesis, Characterization, and Application in the Base-Free Catalytic Isomerization of Allylic Alcohols

The ruthenium(II) arene dimer [{RuCl(μ-Cl)(η6-p-cymene)}2] readily reacted with 4 equiv of guanidines (iPrHN)2CNR (R = iPr (1a), 4-C6H4 tBu (1b), 4-C6H4Br (1c), 2,4,6-C6H2Me3 (1d), 2,6-C6H3 iPr2 (1e)) in toluene at room temperature to generate the mononuclear complexes [RuCl{κ2 N,N′-C(NR)(NiPr)NHiP...

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Veröffentlicht in:	Organometallics 2012-12, Vol.31 (23), p.8301-8311
Hauptverfasser:	Garcı́a-Álvarez, Rocío, Suárez, Francisco J., Dı́ez, Josefina, Crochet, Pascale, Cadierno, Victorio, Antiñolo, Antonio, Fernández-Galán, Rafael, Carrillo-Hermosilla, Fernando
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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