Effect of Ligand Bulk in Ruthenium-Catalyzed Olefin Metathesis: IPr vs IPr

Novel ruthenium catalysts, [RuCl2(IPr*)­(PPh3)­(3-phenylindenylidene)] (1) and [RuCl2(IPr*)­(Py)­(3-phenylindenylidene)] (2), bearing the very bulky ligand IPr* are reported. The complexes were tested in ring closing and cross-metathesis, and their activities were compared to that displayed by [RuCl...

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Veröffentlicht in:	Organometallics 2012-09, Vol.31 (18), p.6514-6517
Hauptverfasser:	Manzini, Simone, Urbina Blanco, César A, Slawin, Alexandra M. Z, Nolan, Steven P
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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