5-Methoxy-Substituted Zirconium Bis-indenyl ansa-Complexes: Synthesis, Structure, and Catalytic Activity in the Polymerization and Copolymerization of Alkenes

A number of 2-methyl-4-aryl-5-methoxy-6-alkylindenes and C 2-symmetric Me2Si-bridged ansa-zirconocenes based on them were synthesized. Zirconocenes were obtained by means of highly effective and scalable racemo-selective synthetic approach based on the use of a Zr tert-butyl amide complex. The struc...

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Veröffentlicht in:Organometallics 2012-07, Vol.31 (14), p.4962-4970
Hauptverfasser: Nifant’ev, Ilya E., Ivchenko, Pavel V., Bagrov, Vladimir V., Churakov, Andrei V., Mercandelli, Pierluigi
Format: Artikel
Sprache:eng
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