Factors Favoring Efficient Bifunctional Catalysis. Study of a Ruthenium(II) Hydrogenation Catalyst Containing an N-Heterocyclic Carbene with a Primary Amine Donor

An alcohol-assisted outer-sphere bifunctional mechanism is proposed for the H2 hydrogenation of ketones catalyzed by the ruthenium­(II) precatalyst [RuCp*­(C–NH2)­py]­PF6 (2; Cp* = pentamethylcyclopentadienyl ligand, C–NH2 = N-heterocyclic carbene (NHC) with a tethered primary amine donor, py = pyri...

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Veröffentlicht in:	Organometallics 2012-03, Vol.31 (6), p.2137-2151
Hauptverfasser:	O, Wylie W. N, Lough, Alan J, Morris, Robert H
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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