Iridium-Catalyzed Asymmetric Ring-Opening of Azabicyclic Alkenes with Phenols

The asymmetric ring-opening of azabicyclic alkenes with a variety of phenols is investigated using an iridium catalyst generated in situ from 2.5 mol % of [Ir(COD)Cl]2 and 5.0 mol % of (S)-BINAP, which afforded the corresponding 1,2-trans-phenoxyamino products in excellent yield (up to 92%) with mod...

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Veröffentlicht in:	Organometallics 2012-04, Vol.31 (8), p.3113-3118
Hauptverfasser:	Fang, Shai, Liang, Xiuli, Long, Yuhua, Li, Xiaolu, Yang, Dingqiao, Wang, Sanyong, Li, Chunrong
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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