New Approach to the Synthesis of 3-Alkyl-1,2-dicarba-closo-dodecaboranes: Reaction of Alkyldichloroboranes with Thallium Dicarbollide

A number of 3-alkyl-substituted 1,2-dicarba-closo-dodecaboranes were prepared in good yields via the reaction of alkyldichloroboranes, which were generated in situ through hydroboration of the corresponding alkenes with a dichloroborane–dioxane complex, with thallium dicarbollides in anhydrous dichl...

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Veröffentlicht in:Organometallics 2012-04, Vol.31 (7), p.2764-2769
Hauptverfasser: Safronov, Alexander V, Shlyakhtina, Natalia I, Hawthorne, M. Frederick
Format: Artikel
Sprache:eng
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