Mo(CO)6-Catalyzed Reduction of N,N-Dimethylthioformamide by Silanes, Germanes, and Stannanes (R3EH) To Produce Trimethylamine and Group 14 Thioethers (R3E–S–ER3)

Treatment of N,N-dimethylthioformamide (DMTF) with a variety of silanes, germanes, and stannanes (R3EH; E = Si, Ge, Sn) in the presence of Mo­(CO)6 leads to facile reduction to trimethylamine and the corresponding group 14 thioethers, (R3E)2S. In the reactions we are able to observe the intermediacy...

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Veröffentlicht in:	Organometallics 2011-12, Vol.30 (24), p.6506-6509
Hauptverfasser:	Arias-Ugarte, Renzo, Sharma, Hemant K., Metta-Magaña, Alejandro J., Pannell, Keith H.
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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