Synthesis and Characterization of Dysprosium and Lanthanum Bis(iminophosphorano)methanide and -methanediide Complexes

Attempts to prepare [Dy{C(PPh2NSiMe3)2}(I)(THF)2] (1) from in situ prepared “[Dy(Bn)2(I)(THF)3]” (“2”; Bn = C6H5CH2) and H2C(PPh2NSiMe3)2 resulted in the isolation of [Dy{CH(PPh2NSiMe3)2}(I)2(THF)] (3) and, on one occasion, a small quantity of [{Dy(CH[PPh2NSiMe3]2)(I)}2(μ-O)] (4). However, attempts...

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Veröffentlicht in:	Organometallics 2010-05, Vol.29 (10), p.2315-2321
Hauptverfasser:	Wooles, Ashley J, Cooper, Oliver J, McMaster, Jonathan, Lewis, William, Blake, Alexander J, Liddle, Stephen T
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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