Design of Sterically Demanding, Electron-Rich Carbene Ligands with the Perimidine Scaffold

A family of N,N‘-disubstituted perimidinium cation salts were employed as precursors to persistent monomeric carbenes with novel molecular architectures and electronic structures. Depending on the substituents, reaction of these 1,3-disubstituted perimidinium cations with LiN(SiMe3)2 led either to d...

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Veröffentlicht in:	Organometallics 2007-05, Vol.26 (11), p.2885-2895
Hauptverfasser:	Bazinet, Patrick, Ong, Tiow-Gan, O'Brien, Julie S, Lavoie, Nathalie, Bell, Eleanor, Yap, Glenn P. A, Korobkov, Ilia, Richeson, Darrin S
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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