Self-Assembled Chloro-Bridged (Arene)ruthenium Metallo-Prisms:  Synthesis and Molecular Structure of Cationic Complexes of the Type [Ru6(η6-arene)6(μ3-tpt-κN)2(μ-Cl)6]6+ (tpt = 2,4,6-tris(pyridinyl)-1,3,5-triazine)

Cationic (arene)ruthenium-based hexanuclear complexes with trigonal-prismatic structures have been synthesized in good yield by self-assembly of only two components:  the dinuclear (arene)ruthenium complexes [Ru(η6-arene)(μ-Cl)Cl]2 (arene = p-PriC6H4Me, C6Me6) react in water with 2,4,6-tris(pyridiny...

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Veröffentlicht in:Organometallics 2007-02, Vol.26 (4), p.915-924
Hauptverfasser: Govindaswamy, Padavattan, Süss-Fink, Georg, Therrien, Bruno
Format: Artikel
Sprache:eng
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