Mesitylgold(I) and Silver(I) Perfluorocarboxylates as Precursors of Supramolecular Au/Ag Systems

Reaction of [Ag(CF3CO2)] with tetrahydrothiophene (tht) (2:1) in dichloromethane leads to the synthesis of [Ag4(CF3CO2)4(tht)2] (1), which further reacts with mesitylgold(I) ([Au(mes)]) (1:1) to afford [AuAg4(mes)(CF3CO2)4(tht)] n (3). Treatment of [Au(mes)] with [Ag(RCO2)] (R = CF3, CF2CF3) and tht...

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Veröffentlicht in:	Organometallics 2006-08, Vol.25 (18), p.4307-4315
Hauptverfasser:	Fernández, Eduardo J, Laguna, Antonio, López-de-Luzuriaga, José M, Montiel, M, Olmos, M. Elena, Pérez, Javier, Puelles, Raquel C
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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