New Insights into Xantphos/Pd-Catalyzed C−N Bond Forming Reactions:  A Structural and Kinetic Study

Both (Xantphos)Pd(dba) and Pd(Xantphos)2 were identified in mixtures of Pd2(dba)3 and Xantphos by use of 31P NMR and independent syntheses. At high ligand concentrations, Pd(Xantphos)2 was found to be the predominant species. Reaction calorimetry was employed to determine whether the formation of Pd...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Organometallics 2006-01, Vol.25 (1), p.82-91
Hauptverfasser:	Klingensmith, Liane M, Strieter, Eric R, Barder, Timothy E, Buchwald, Stephen L
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!