Reaction of Nitromethane with an Iridium Pincer Complex. Multiple Binding Modes of the Nitromethanate Anion

The reaction of nitromethane with (PCP)Ir (PCP = κ3-2,6-( t Bu2PCH2)2C6H3) yields the bidentate O,O-ligated nitromethanate complex (PCP)Ir(H)(κ2-O,O-NO2CH2) (1). Reaction of 1 with CO affords a CO adduct with a mono-oxygen-ligated nitromethanate, 2, which represents the first characterized transitio...

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Veröffentlicht in:	Organometallics 2006-02, Vol.25 (5), p.1303-1309
Hauptverfasser:	Zhang, Xiawei, Emge, Thomas J, Ghosh, Rajshekhar, Krogh-Jespersen, Karsten, Goldman, Alan S
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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