Transfer Hydrogenation of Acetophenone Catalyzed by Half-Sandwich Ruthenium(II) Complexes Containing Amino Amide Ligands. Detection of the Catalytic Intermediates by Electrospray Ionization Mass Spectrometry

A series of natural amino acid (alanine, valine, phenylalanine, and isoleucine) amides have been synthesized and fully characterized. They have been used as supporting ligands in the Ru(II)-catalyzed asymmetric transfer hydrogenation (ath) of acetophenone in the presence of i-PrOH/KOH. Secondary ami...

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Veröffentlicht in:	Organometallics 2005-11, Vol.24 (24), p.5836-5844
Hauptverfasser:	Pelagatti, Paolo, Carcelli, Mauro, Calbiani, Francesca, Cassi, Claudio, Elviri, Lisa, Pelizzi, Corrado, Rizzotti, Umberto, Rogolino, Dominga
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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