Organometallic Zwitterions:  Arylpalladium(II) (Pincer) Complexes with a Tethered Sulfato Group as para-Substituent

Arylpalladium (NCN-pincer) complexes [NBu4][O3SO(CH2) n SiMe2NCNPdCl] (n = 3 (1a) and n = 6 (1b)) with a tethered sulfato group as para-substituent were synthesized. These novel complexes combine an anionic sulfato group and a neutral NCN−Pd−Cl group in one molecule. Furthermore, 1a,b were converted...

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Veröffentlicht in:Organometallics 2005-12, Vol.24 (25), p.6147-6158
Hauptverfasser: van de Coevering, Rob, Kuil, Mark, Alfers, Alfred P, Visser, Tom, Lutz, Martin, Spek, Anthony L, Klein Gebbink, Robertus J. M, van Koten, Gerard
Format: Artikel
Sprache:eng
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