Synthesis and Characterization of Neutral and Cationic Intramolecularly Coordinated Aluminum Compounds. Structural Determination of [(Pytsi)AlMe]+[MeB(C6F5)3]- [(Pytsi = C(SiMe3)2SiMe2(2-C5H4N)]

The synthesis and structure of neutral and cationic aluminum compounds equipped with the intramolecular donating C(SiMe3)2SiMe2(2-C5H4N) ligand denoted by Pytsi is described. The compounds (Pytsi)AlMe2 (1), (Pytsi)AlEt2 (2), [(Pytsi)AlMe]+[MeB(C6F5)3]- (3), and [(Pytsi)AlMe(thf)]+[MeB(C6F5)3]- (3·th...

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Veröffentlicht in:Organometallics 2005-12, Vol.24 (25), p.6120-6125
Hauptverfasser: Stanga, Olimpiu, Lund, Clinton L, Liang, Huan, Quail, J. Wilson, Müller, Jens
Format: Artikel
Sprache:eng
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