Synthesis and Characterization of Neutral and Cationic Intramolecularly Coordinated Aluminum Compounds. Structural Determination of [(Pytsi)AlMe]+[MeB(C6F5)3]- [(Pytsi = C(SiMe3)2SiMe2(2-C5H4N)]
The synthesis and structure of neutral and cationic aluminum compounds equipped with the intramolecular donating C(SiMe3)2SiMe2(2-C5H4N) ligand denoted by Pytsi is described. The compounds (Pytsi)AlMe2 (1), (Pytsi)AlEt2 (2), [(Pytsi)AlMe]+[MeB(C6F5)3]- (3), and [(Pytsi)AlMe(thf)]+[MeB(C6F5)3]- (3·th...
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Veröffentlicht in: | Organometallics 2005-12, Vol.24 (25), p.6120-6125 |
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Hauptverfasser: | , , , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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