Alkylation, Insertion of Isocyanides, and Intramolecular Rearrangement Processes in Azatantalacyclopentene Complexes. X-ray Crystal Structure of [TaCpMe2(CHCHCMe2NAr-κ2 C,N)] (Cp = η5-C5Me5; Ar = 2,6-Me2C6H3)

Chloro methyl and dimethyl azatantalacyclopentene complexes [TaCp*Cl2 - x Me x (CHCHCMe2NAr-κ2 C,N)] (Cp* = η5-C5Me5; Ar = 2,6-Me2C6H3; x = 1, 2; 2, 3) can be prepared by reaction of [TaCp*Cl2(CHCHCMe2NAr-κ2 C,N)] (1a) with dimethylzinc and chloromethylmagnesium, respectively. Reaction of 1a with di...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Organometallics 2005-07, Vol.24 (14), p.3552-3560
Hauptverfasser:	Galakhov, Mikhail V, Gómez, Manuel, Gómez-Sal, Pilar, Velasco, Patricia
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!