Deprotonation of μ-Vinyliminium Ligands in Diiron Complexes:  A Route for the Synthesis of Mono- and Polynuclear Species Containing Novel Multidentate Ligands

The Cβ−H hydrogen in the diiron vinyliminium complexes [Fe2{μ-η1:η3-Cγ(R‘)CβHCαN(Me)(R)}(μ-CO)(CO)(Cp)2][SO3CF3] (R = Me, 1; R = Bz, 2 (Bz = CH2Ph); R = Xyl, 3 (Xyl =2,6-Me2C6H3)) is easily removed by sodium hydride; different products are consequently formed, depending on the nature of the substi...

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Veröffentlicht in:	Organometallics 2005-05, Vol.24 (10), p.2297-2306
Hauptverfasser:	Busetto, Luigi, Marchetti, Fabio, Zacchini, Stefano, Zanotti, Valerio
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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