Pressure Dependence of the Carbon Dioxide/Cyclohexene Oxide Coupling Reaction Catalyzed by Chromium Salen Complexes. Optimization of the Comonomer-Alternating Enchainment Pathway

The rate of the copolymerization reaction of cyclohexene oxide and carbon dioxide in the presence of (salen)CrIIIN3 and various cocatalysts has been determined as a function of CO2 pressure. Carbon dioxide insertion into the (salen)Cr-alkoxide intermediates, afforded following epoxide ring-opening,...

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Veröffentlicht in:	Organometallics 2005-01, Vol.24 (1), p.144-148
Hauptverfasser:	Darensbourg, Donald J, Mackiewicz, Ryan M, Billodeaux, Damon R
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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