Highly Efficient Asymmetric Hetero-Diels−Alder Reactions of Carbonyl Compounds Catalyzed by Lewis Acid Platinum Complexes of Conformationally Flexible NUPHOS-Type Diphosphines

Conformationally flexible NUPHOS-type diphosphines have been resolved as their diastereopure platinum BINOLate complexes δ- and λ-[(NUPHOS)Pt{(S)-BINOL}] and the corresponding enantiopure Lewis acids δ- and λ-[(NUPHOS)Pt(OTf)2], being generated by protonation with trifluoromethanesulfonic acid, act...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Organometallics 2004-12, Vol.23 (26), p.6127-6133
Hauptverfasser:	Doherty, Simon, Knight, Julian G, Hardacre, Christopher, Lou, He−Kuan, Newman, Colin R, Rath, Rakesh K, Campbell, Sarah, Nieuwenhuyzen, Mark
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!