A Stable Ruthenium Catalyst for Productive Olefin Metathesis

A Stable Ruthenium Catalyst for Productive Olefin Metathesis

New ruthenium carbene complexes 5 and 6, containing a rigid bicyclic phosphine moiety, have been prepared, and the structure of 5 has been unambiguously established by single-crystal X-ray diffraction studies. These ruthenium-based complexes show excellent stability to air and moisture, can be recyc...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Organometallics 2004-10, Vol.23 (21), p.4824-4827
Hauptverfasser: Forman, Grant S, McConnell, Ann E, Hanton, Martin J, Slawin, Alexandra M. Z, Tooze, Robert P, van Rensburg, Werner Janse, Meyer, Wolfgang H, Dwyer, Cathy, Kirk, Megan M, Serfontein, D. Wynand
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 4827
container_issue 21
container_start_page 4824
container_title Organometallics
container_volume 23
creator Forman, Grant S
McConnell, Ann E
Hanton, Martin J
Slawin, Alexandra M. Z
Tooze, Robert P
van Rensburg, Werner Janse
Meyer, Wolfgang H
Dwyer, Cathy
Kirk, Megan M
Serfontein, D. Wynand
description New ruthenium carbene complexes 5 and 6, containing a rigid bicyclic phosphine moiety, have been prepared, and the structure of 5 has been unambiguously established by single-crystal X-ray diffraction studies. These ruthenium-based complexes show excellent stability to air and moisture, can be recycled by chromatography, and are available from simple precursors. They are efficient catalysts for various metathesis reactions, particularly for applications where high selectivity is required.
doi_str_mv 10.1021/om049370c
format Article
fullrecord <record><control><sourceid>istex_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1021_om049370c</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>ark_67375_TPS_B72H2T9W_J</sourcerecordid><originalsourceid>FETCH-LOGICAL-a361t-1f615249ec108469e375a96bf83426cbb599320cc1c948fb5ea010d5d7bf33bb3</originalsourceid><addsrcrecordid>eNptz0FLwzAYxvEgCs7pwW-QiwcP1TdJmyzgZQ51ymTDVTyGJE2ws1slScV9eyuTnTy9lx8P7x-hcwJXBCi5bteQSybAHqABKShkHHJyiAZABc8EY-wYncS4AgAuGB2gmzFeJm0ah1-69O42dbfGE510s40J-zbgRWirzqb6y-F543y9wc8u6Z7GOp6iI6-b6M7-7hC93t-Vk2k2mz88TsazTDNOUkY871_JpbMERjmXjolCS278iOWUW2MKKRkFa4mV-cibwmkgUBWVMJ4xY9gQXe52bWhjDM6rz1CvddgqAuo3W-2ze5vtbB2T-95DHT5UXywKVS6W6lbQKS3lm3rq_cXOaxvVqu3Cpi_5Z_cHFgJkzA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>A Stable Ruthenium Catalyst for Productive Olefin Metathesis</title><source>ACS Publications</source><creator>Forman, Grant S ; McConnell, Ann E ; Hanton, Martin J ; Slawin, Alexandra M. Z ; Tooze, Robert P ; van Rensburg, Werner Janse ; Meyer, Wolfgang H ; Dwyer, Cathy ; Kirk, Megan M ; Serfontein, D. Wynand</creator><creatorcontrib>Forman, Grant S ; McConnell, Ann E ; Hanton, Martin J ; Slawin, Alexandra M. Z ; Tooze, Robert P ; van Rensburg, Werner Janse ; Meyer, Wolfgang H ; Dwyer, Cathy ; Kirk, Megan M ; Serfontein, D. Wynand</creatorcontrib><description>New ruthenium carbene complexes 5 and 6, containing a rigid bicyclic phosphine moiety, have been prepared, and the structure of 5 has been unambiguously established by single-crystal X-ray diffraction studies. These ruthenium-based complexes show excellent stability to air and moisture, can be recycled by chromatography, and are available from simple precursors. They are efficient catalysts for various metathesis reactions, particularly for applications where high selectivity is required.</description><identifier>ISSN: 0276-7333</identifier><identifier>EISSN: 1520-6041</identifier><identifier>DOI: 10.1021/om049370c</identifier><language>eng</language><publisher>American Chemical Society</publisher><ispartof>Organometallics, 2004-10, Vol.23 (21), p.4824-4827</ispartof><rights>Copyright © 2004 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a361t-1f615249ec108469e375a96bf83426cbb599320cc1c948fb5ea010d5d7bf33bb3</citedby><cites>FETCH-LOGICAL-a361t-1f615249ec108469e375a96bf83426cbb599320cc1c948fb5ea010d5d7bf33bb3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/om049370c$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/om049370c$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,776,780,2752,27053,27901,27902,56713,56763</link.rule.ids></links><search><creatorcontrib>Forman, Grant S</creatorcontrib><creatorcontrib>McConnell, Ann E</creatorcontrib><creatorcontrib>Hanton, Martin J</creatorcontrib><creatorcontrib>Slawin, Alexandra M. Z</creatorcontrib><creatorcontrib>Tooze, Robert P</creatorcontrib><creatorcontrib>van Rensburg, Werner Janse</creatorcontrib><creatorcontrib>Meyer, Wolfgang H</creatorcontrib><creatorcontrib>Dwyer, Cathy</creatorcontrib><creatorcontrib>Kirk, Megan M</creatorcontrib><creatorcontrib>Serfontein, D. Wynand</creatorcontrib><title>A Stable Ruthenium Catalyst for Productive Olefin Metathesis</title><title>Organometallics</title><addtitle>Organometallics</addtitle><description>New ruthenium carbene complexes 5 and 6, containing a rigid bicyclic phosphine moiety, have been prepared, and the structure of 5 has been unambiguously established by single-crystal X-ray diffraction studies. These ruthenium-based complexes show excellent stability to air and moisture, can be recycled by chromatography, and are available from simple precursors. They are efficient catalysts for various metathesis reactions, particularly for applications where high selectivity is required.</description><issn>0276-7333</issn><issn>1520-6041</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><recordid>eNptz0FLwzAYxvEgCs7pwW-QiwcP1TdJmyzgZQ51ymTDVTyGJE2ws1slScV9eyuTnTy9lx8P7x-hcwJXBCi5bteQSybAHqABKShkHHJyiAZABc8EY-wYncS4AgAuGB2gmzFeJm0ah1-69O42dbfGE510s40J-zbgRWirzqb6y-F543y9wc8u6Z7GOp6iI6-b6M7-7hC93t-Vk2k2mz88TsazTDNOUkY871_JpbMERjmXjolCS278iOWUW2MKKRkFa4mV-cibwmkgUBWVMJ4xY9gQXe52bWhjDM6rz1CvddgqAuo3W-2ze5vtbB2T-95DHT5UXywKVS6W6lbQKS3lm3rq_cXOaxvVqu3Cpi_5Z_cHFgJkzA</recordid><startdate>20041011</startdate><enddate>20041011</enddate><creator>Forman, Grant S</creator><creator>McConnell, Ann E</creator><creator>Hanton, Martin J</creator><creator>Slawin, Alexandra M. Z</creator><creator>Tooze, Robert P</creator><creator>van Rensburg, Werner Janse</creator><creator>Meyer, Wolfgang H</creator><creator>Dwyer, Cathy</creator><creator>Kirk, Megan M</creator><creator>Serfontein, D. Wynand</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20041011</creationdate><title>A Stable Ruthenium Catalyst for Productive Olefin Metathesis</title><author>Forman, Grant S ; McConnell, Ann E ; Hanton, Martin J ; Slawin, Alexandra M. Z ; Tooze, Robert P ; van Rensburg, Werner Janse ; Meyer, Wolfgang H ; Dwyer, Cathy ; Kirk, Megan M ; Serfontein, D. Wynand</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a361t-1f615249ec108469e375a96bf83426cbb599320cc1c948fb5ea010d5d7bf33bb3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2004</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Forman, Grant S</creatorcontrib><creatorcontrib>McConnell, Ann E</creatorcontrib><creatorcontrib>Hanton, Martin J</creatorcontrib><creatorcontrib>Slawin, Alexandra M. Z</creatorcontrib><creatorcontrib>Tooze, Robert P</creatorcontrib><creatorcontrib>van Rensburg, Werner Janse</creatorcontrib><creatorcontrib>Meyer, Wolfgang H</creatorcontrib><creatorcontrib>Dwyer, Cathy</creatorcontrib><creatorcontrib>Kirk, Megan M</creatorcontrib><creatorcontrib>Serfontein, D. Wynand</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><jtitle>Organometallics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Forman, Grant S</au><au>McConnell, Ann E</au><au>Hanton, Martin J</au><au>Slawin, Alexandra M. Z</au><au>Tooze, Robert P</au><au>van Rensburg, Werner Janse</au><au>Meyer, Wolfgang H</au><au>Dwyer, Cathy</au><au>Kirk, Megan M</au><au>Serfontein, D. Wynand</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A Stable Ruthenium Catalyst for Productive Olefin Metathesis</atitle><jtitle>Organometallics</jtitle><addtitle>Organometallics</addtitle><date>2004-10-11</date><risdate>2004</risdate><volume>23</volume><issue>21</issue><spage>4824</spage><epage>4827</epage><pages>4824-4827</pages><issn>0276-7333</issn><eissn>1520-6041</eissn><abstract>New ruthenium carbene complexes 5 and 6, containing a rigid bicyclic phosphine moiety, have been prepared, and the structure of 5 has been unambiguously established by single-crystal X-ray diffraction studies. These ruthenium-based complexes show excellent stability to air and moisture, can be recycled by chromatography, and are available from simple precursors. They are efficient catalysts for various metathesis reactions, particularly for applications where high selectivity is required.</abstract><pub>American Chemical Society</pub><doi>10.1021/om049370c</doi><tpages>4</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0276-7333
ispartof Organometallics, 2004-10, Vol.23 (21), p.4824-4827
issn 0276-7333
1520-6041
language eng
recordid cdi_crossref_primary_10_1021_om049370c
source ACS Publications
title A Stable Ruthenium Catalyst for Productive Olefin Metathesis
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-10T10%3A19%3A43IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-istex_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=A%20Stable%20Ruthenium%20Catalyst%20for%20Productive%20Olefin%20Metathesis&rft.jtitle=Organometallics&rft.au=Forman,%20Grant%20S&rft.date=2004-10-11&rft.volume=23&rft.issue=21&rft.spage=4824&rft.epage=4827&rft.pages=4824-4827&rft.issn=0276-7333&rft.eissn=1520-6041&rft_id=info:doi/10.1021/om049370c&rft_dat=%3Cistex_cross%3Eark_67375_TPS_B72H2T9W_J%3C/istex_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true