Rational Synthesis of Platinabenzenes
Treatment of Cp*Pt(CO)I (8) with two nucleophilic (Z)-3-(2-lithiovinyl)cyclopropenes provides a rational synthesis of platinabenzenes 6 and 7. The intermediate σ-vinyl complexes 9 and 10 are also isolated from the reaction mixtures and convert cleanly to the corresponding platinabenzenes in near-qua...
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| Veröffentlicht in: | Organometallics 2004-03, Vol.23 (6), p.1174-1176 |
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| Sprache: | eng |
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| container_end_page | 1176 |
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| container_issue | 6 |
| container_start_page | 1174 |
| container_title | Organometallics |
| container_volume | 23 |
| creator | Landorf, Christopher W. Jacob, Volker Weakley, Timothy J. R. Haley, Michael M. |
| description | Treatment of Cp*Pt(CO)I (8) with two nucleophilic (Z)-3-(2-lithiovinyl)cyclopropenes provides a rational synthesis of platinabenzenes 6 and 7. The intermediate σ-vinyl complexes 9 and 10 are also isolated from the reaction mixtures and convert cleanly to the corresponding platinabenzenes in near-quantitative yield. |
| doi_str_mv | 10.1021/om034371a |
| format | Article |
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| ispartof | Organometallics, 2004-03, Vol.23 (6), p.1174-1176 |
| issn | 0276-7333 1520-6041 |
| language | eng |
| recordid | cdi_crossref_primary_10_1021_om034371a |
| source | American Chemical Society Journals |
| title | Rational Synthesis of Platinabenzenes |
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