Cationic Platinum(II) Carboxylato Complexes Are Competent in Catalytic Arene C−H Activation under Mild Conditions
A combination of ESI-MS and kinetic studies establishes that the PtII-catalyzed H/D exchange between benzene and acetic acid-d 4 proceeds with high turnover number in acetic acid solution. For the catalytic cycle, the resting state is identified as the cationic (diimine)PtII(acetato)(acetic acid) co...
Gespeichert in:
| Veröffentlicht in: | Organometallics 2004-06, Vol.23 (12), p.3031-3036 |
|---|---|
| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
Schreiben Sie den ersten Kommentar!