The First Platinum-Catalyzed Hydroamination of Ethylene

The platinum-catalyzed hydroamination of ethylene with aniline is reported for the first time. Using PtBr2 as a catalyst precursor in n-Bu4PBr under 25 bar of ethylene pressure affords N-ethylaniline with 80 turnovers after 10 h at 150 °C. The reaction simultaneously produces 2-methylquinoline in ca...

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Veröffentlicht in:	Organometallics 2004-03, Vol.23 (6), p.1264-1268
Hauptverfasser:	Brunet, Jean-Jacques, Cadena, Magali, Chu, Ngoc Chau, Diallo, Ousmane, Jacob, Kane, Mothes, Emmanuelle
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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