Coordinatively Unsaturated Ruthenium Phosphine Half-Sandwich Complexes:  Correlations to Structure and Reactivity

A number of 16e two-legged piano-stool complexes [Cp*Ru(PP)][BAr‘4] have been prepared by reaction of NaBAr‘4 with either [Cp*RuCl(PP)] (PP = (PEt3)2, iPr2PCH2CH2PiPr2 (dippe), (PPh3)2) or [Cp*RuCl(PR3)] plus PR3 (PR3 = PMeiPr2, PPhiPr2) in fluorobenzene under argon. The complexes [Cp*Ru(PEt3)2][BAr...

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Veröffentlicht in:	Organometallics 2002-11, Vol.21 (24), p.5334-5346
Hauptverfasser:	Aneetha, Halikhedkar, Jiménez-Tenorio, Manuel, Puerta, M. Carmen, Valerga, Pedro, Sapunov, Valentin N, Schmid, Roland, Kirchner, Karl, Mereiter, Kurt
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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